Roaming dynamics in ketene isomerization
نویسندگان
چکیده
منابع مشابه
Thermal Dissociation and Roaming Isomerization of Nitromethane: Experiment and Theory.
The thermal decomposition of nitromethane provides a classic example of the competition between roaming mediated isomerization and simple bond fission. A recent theoretical analysis suggests that as the pressure is increased from 2 to 200 Torr the product distribution undergoes a sharp transition from roaming dominated to bond-fission dominated. Laser schlieren densitometry is used to explore t...
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ژورنال
عنوان ژورنال: Theoretical Chemistry Accounts
سال: 2014
ISSN: 1432-881X,1432-2234
DOI: 10.1007/s00214-014-1507-4